P: ISSN No. 2394-0344 RNI No.  UPBIL/2016/67980 VOL.- VII , ISSUE- V August  - 2022
E: ISSN No. 2455-0817 Remarking An Analisation
A Review on Fluoride Consumption and Its Remedies In Groundwater In Endemic Villages of Hathras District, U.P.
Paper Id :  16321   Submission Date :  20/08/2022   Acceptance Date :  22/08/2022   Publication Date :  25/08/2022
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Gayatri Kumari
Assistant Professor
Chemistry
Saraswati Degree College
Hathras,U. P., India
Abstract Water being pumped up from underground sources and used for domestic as well as irrigation purposes in several parts of Hathras division is high on fluoride content and is alkaline besides containing a high volume of heavy metals. Samples of ground water collected from different villages of Hathras district have recorded more content of fluoride in the ground water. The water also contains a large volume of TDS (total dissolved solids), high degree of PH level (alkaline) and excess quantity of iron ore. Today, it is a known fact that the groundwater quality is degrading day by day, which is a serious matter of concern, as poor quality water causes threats to health and hygiene of living beings. Presence of large amount of fluoride in ground water is associated with dental and skeletal fluorosis (>1.5 mg/l) and inadequate amount with dental caries[1] (<1 g/l).The permissible consumption of fluoride is recommended to be 0.05 /day/kg of body weight for maintaining good health. The average weight of villagers of Hathras district is about 50 to 60 kg. Thus per day permissible consumption of fluoride is about 2.5 to 3mg. The scientific data on fluoride contents in food indicates that about 2 to 3 mg fluoride is consumed from food, milk and tea alone leaving very little scope for the consumption through water. As it is very difficult to isolate the food having high fluoride content in the daily food chain, it was therefore decided to install reverse osmosis plants for water defluoridation. Within one year of installation of Reverse Osmosis (RO) plants, the interaction with the communities started giving positive signs of general improvement in health and wellbeing due to reduction in incidences of waterborne diseases and other health related problems of the villagers. Hence, on the basis of above facts, it was decided to give a review article on the content of fluoride consumptions and its remedies in ground water of different endemic villages of Hathras district, UttarPradesh , India.
Keywords Fluoride In Ground Water, Reverse Osmosis, Fluorosis, Affected Villages of Hathras.
Introduction
Water is the essential requirement for living specially clean water but its availability is decreasing day by day. Now water is getting harmful due to the anthropogenic activities such as urbanization, agriculture and industrialization. It was observed during the interaction with villagers of Hathras district that they were suffering from dental fluorosis, skeletal deformaties and other associated problems caused due to the excessive fluoride ingestion2. The water test did not show the levels of fluoride higher than [2] mg/l. From the literature survey it was observed that the fluoride ingestion is caused not only through water but also through food, tea, toothpaste , milk etc. Therefore, to control the over intake of fluoride, the only controllable aspect was water. Hence, there is a need for and concern over the protection and management of surface and groundwater quality. The Government of India has emphasized the objective of safe drinking water supply to the population and so desired by Hathras district. State Government is responsible for undertaking water quality assessment of all the groundwater sources used for public water supply schemes. These industries use huge quantity of water for processing and release most of the water in the form of effluent. The waste water being generated is discharged into the nearby water channels. Likewise the geochemical and morphological structure changes and for other subsequent uses. It is estimated that about 200 million people, from among 25 nations over world , may suffer from from fluorosis and the causes have been resulted to fluoride contamination in groundwater including India[3-4].Considering the above aspects of ground water contamination of fluoride, the present review was undertaken to investigate the impact of the groundwater of Hathras district and its adjoining villages.
Aim of study The purpose of this paper is to reveal the harmful effects of consumption of fluoride through ground water on human being of endemic villages of Hathras district and their simultaneous needs for the urgency of the necessary steps to be taken for the preservations and up-gradation of water quality. Hence, the drinking water quality in the study area is not scaled as per the standard values of the concern parameters and showing alarming levels of pollutants. Therefore, it need some degree of treatment before utilizing it for any consumption purpose.
Review of Literature

From the review of literature, it was observed that fluoride occurs in almost all waters from trace to high concentrations[5]. Its concentration in natural water depends on various factors such as temperature, PH, solubility of fluorine bearing materials, anion exchange capacity of aquifer materials and the nature of geological formations drained by water and contact time of water with a particular formation.  Among all minerals, fluoride is the mineral having both lower (0.6 mg/l) and upper (1.2 mg/l) limits of concentration in drinking water, with identified health effect and benefits for human beings[6,7].

Generally, fluoride content in water between 1.5 mg/l and 2.0 mg/l may lead to dental motting, which is characterized initially by opaque white patches on the teeth and in advanced stages leads to dental fluorosis followed by pitting of teeth surfaces. When fluoride content is exceeded between 4.8gm/l then, skeletal fluorosis[8] may occur in children upto the age of 12 years. High content of fluoride causes an increase in bone density leading to thickness of long bones and calcification of ligaments. The symptoms may include the mild rheumatic/arthritic pain in the hounts and muscles to severe pain in the cervical spine region along with stiffness and rigidity of the joints[9]. The severe condition of fluorosis depends on the concentration of fluoride in the drinking water, daily intake, continuity and duration of exposure and climatic conditions.

Ground water is considered as the major source of drinking water in most places on earth. Generally, people use groundwater for drinking and other domestic household work without any physical and chemical treatment. This practice is not a healthy one and it may lead to several health disorders to human being. But this problem can not be solved because there is lack of treated piped water supply system in several part of developing countries especially rural areas. The problem of high fluoride in groundwater has been reported by several researchers not only in India but all over the world. It was reported that when groundwater fluctuation was within 4.5 m below ground level, fluoride concentration was high when the water level was low and the fluoride concentration decreases with the rise in water table[10]. This was due to direct evaporation of groundwater from these wells. If the groundwater fluctuation was beyond 4.5m below ground level, the concentration of fluoride measured in groundwater after the monsoonal rains were higher than the preceding months. This was because evaporation resulted in the precipitation of fluoride rich slats on the soil which reached the groundwater along with percolation rainwater. Thus, the treatment of groundwater especially for fluoride before using it for drinking purposes is very essential in India[11].

The occurrence and development of endemic fluorosis have its roots in the high fluoride content in water, air and soil of which water is perhaps the major contributor[12]. In India, the fluorosis is observed at the concentration of more than 1.20mg/l and dental caries at the concentration of less than 0.60 mg/l in the drinking water[13]. Due to larger societal implication and major human concern, it is therefore crucial to understand the origin and distribution of fluoride in groundwater[14].fluoride contamination in groundwater in India is mostly concentrated at western and southern India. The Indo-Gangetic Plain (IGP), covers a vast area of northern India and constitute eleven Indian states with habitation of approximately 43% of the Indian population[15]. Being the most populated river basin in the world, only a few work has been done from the IGP focusing on the fluoride contamination in groundwater[16]. A high concentration of fluoride is reported in the major districts of these states but no such regional studies have been carried out to understand the fluoride enrichment process.

Methodology
Different research journals and research papers and people of that area were consulted regarding that research review.
Result and Discussion

Fluoride is a chemical element that is found most frequently groundwater and has become one of the most important toxicological environment hazards globally. From the review of literature, it has been found that the occurrence of fluoride in groundwater is due to weathering and leaching of fluoride bearing minerals from rocks and sediments. Fluoride when ingested in small quantities (<0.5 mg/l) is beneficial in promoting dental health by reducing dental caries, whereas higher concentrations (>1.5 mg/l) may cause fluorosis.
Several studies have shown that the fluoride exposure in humans is related to (1) fluoride concentration in drinking water ,  (2) duration of consumption, and (3) climate of the area. In hotter climates where water consumption is greater, exposure doses of fluoride need to be modified based on mean fluoride intake. Various cost-effective and simple techniques are already known, but the benefits of such techniques have not reached the rural affected population due to limitations. Therefore, there is a need to develop workable strategies to provide fluoride safe drinking water to rural communities.

Conclusion It is known that the rapid growth of population in the area increases its residences dependence more on groundwater but the groundwater quality is not found to be up to the mark. People must aware about the utilization of groundwater and how their activities may lead to contamination of ground sources. The data derived from the above studies shown that the contamination of fluoride through water or any other sources is harmful for human being. It was observed that most of the samples in the study area of endemic villages of Hathras district (U.P.) correspond to low fluoride value which attest limited role of fluoride bearing lithology in the enrichment process. Although few point sources of anthropogenic contamination have been identified in these areas, however, more detailed field study is recommended to ascertain the source. The result of this work has filled a knowledge gap by providing a broad framework of base line data, which can be used for intense investigation employing detailed sampling from specific locations for its chemical and isotopic analysis. People of Hathras district should be known by the utilization and contamination of groundwater. Certain methods such as ground water recharging, water use education, efficient irrigation methods, should be adopted by these people for sustainable water management and development of endemic villages of Hathras district. Use of submersible pumps and jet pumps should be monitored and controlled for proper water withdrawal to preserve the ground water table level. Ponds are proposed to be constructed in which water can be stored during rainy season and can serve cattle for drinking.
Suggestions for the future Study People of Hathras district should be known by the utilization and contamination of groundwater. Certain methods such as ground water recharging, water use education, efficient irrigation methods, should be adopted by these people for sustainable water management and development of endemic villages of Hathras district. Use of submersible pumps and jet pumps should be monitored and controlled for proper water withdrawal to preserve the ground water table level. Ponds are proposed to be constructed in which water can be stored during rainy season and can serve cattle for drinking.
References
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