P: ISSN No. 2394-0344 RNI No.  UPBIL/2016/67980 VOL.- VII , ISSUE- IX December  - 2022
E: ISSN No. 2455-0817 Remarking An Analisation
Physicochemical Analysis of Groundwater Sample of Neemod Village of Neemkathana Block of Sikar, India
Paper Id :  16946   Submission Date :  12/12/2022   Acceptance Date :  22/12/2022   Publication Date :  25/12/2022
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Santosh Kumar Verma
Associate Profesor
Department Of Chemistry
SNKP Govt. PG College Neemkathana
,Rajasthan, India
Suresh Kumar Verma
Associate Professor
Department Of Chemistry
Government Science PG College Sikar
Neemkathama, Rajasthan, India
Abstract Physico-chemical analysis of groundwater of Neemod village of Neemkathana block is taken to evaluate its suitability for domestic use. Groundwater samples were collected from the bore well for the assessment period from Jan-2022 to Dec-2022. Physico-chemical parameters are selected: pH, hardness, alkalinity, chloride, nitrate, sulphate, fluoride, and TDS. Methods were used as suggested by BIS (IS 10500: 2012 estimation of acceptable limits and permissible limits for selected parameters.
Keywords Groundwater, Physio-Chemical Parameters, WHO, BIS, TDS.
Introduction
The mineralogic composition of the aquifer, and the contact time, affect the mineralogic composition of groundwater and the Composition affecting processes are redox, ion exchange, hydrolysis, dissolution, precipitation, biochemical reactions, etc., (Mathess, 1982).
Aim of study Large scale open cast mining creating huge problems to ecosystem of the block. Fine dust particles percolating upto aquifer system and changing the quality of groundwater and portability of water continuously decreasing. Present study will provide important information to villagers.
Review of Literature

Britannica the world's most important dictionary has defined water "A substance composed of the chemical elements hydrogen and oxygen and existing in gaseous, liquid, and solid states. It is one of the most plentiful and essential of compounds. A tasteless and odourless liquid at room temperature, it has the important ability to dissolve many other substances. Indeed, the versatility of water as a solvent is essential to living organisms" (Zumdahl, 2021).

Amnate (2009) states that the total volume of water on the earth is 1.386 billion km3 which comprises of 97.5% salty water and 2.5% fresh water (can be used for drinking), and only 0.3% of water is in liquid phase and other 99.70% of water is in solid (ICE) phase on the earth.

Main Text

Table1:  Hydrogeological Formation of Neemkathana Block

S.No.

Village

Hydrological Formation

1

Guhala

Older Alluvium

2

Tiwari Ka Bas

Older Alluvium

3

Sirohi

Older Alluvium

4

Bhagoth

Older Alluvium

5

Guhala

Older Alluvium

6

Cheeplata

Quartzite

7

Ganwari            

Quartzite

8

Kishanpura

Quartzite

9

Mahawa

Quartzite

10

Mawanda Kalan

Quartzite

11

Nayabas

Quartzite

12

Neemod      

Quartzite

13

Sanwalpura Tanwran   

Quartzite

14

Gordhanpura

Quartzite

15

Mawanda Kalan

Quartzite

16

Mahawa

Quartzite

17

Mandoli

Quartzite

18

Ajmeri

Quartzite

Table 1 shows the hydrological formations of the Neemkathana block, which is almost quartzite which is a metamorphic rock, and in the remaining is older alluvium. Metamorphic rocks are rich in minerals containing fluoride (Johns et al., 1967; Frencken, 1992). 

In India, water quality standards were first published in 1983. Second revision (IS -10500: 2012) with the objective of assessing the quality of given water resources and checking the water treatment, which is in alignment with available specifications, with both acceptable and permissible limits.

The Bureau of Indian Standards, developed Indian standards for drinking water BIS(SI 10500:2012), which consists of six tables as Organoleptic and Physical Parameters, General Parameters Concerning Substances Undesirable in Excessive Amounts, Parameters Concerning Toxic Substances, Parameters Concerning Radioactive Substances, Pesticide Residues Limits, and Test Method and Bacteriological Quality of Drinking Water.

Study Area

Geographical location Neemod village 27.2475° N, 74.7850° E with area of 1435 hectares and a population is 1873. As surface water is unavailable so peoples are dependent on groundwater. The distance between the village from Neemkathana is 7km.






Material and Methods

Table 2: List of Parameters and Methods of Determination

Parameters

Methods of determination

pH

pH Meter

TH (mg/L)

EDTA Method

Ca (mg/L)

Titration Method

Mg (mg/L)

Titration Method

TDS (mg/L)

Potentiometric Method

F- (mg/L)

UV Spectrophotometric Method

SO42- (mg/L)

Turbid meter Method

NO3- (mg/L)

Spectrophotometer

Result and Discussion

Assessment of groundwater of Neemod village in Neemkathana block

Groundwater samples from Neemod village were collected for the assessment period of Jan-2022 to Dec-2022 and analyzed for selected physico-chemical parameters. The results of physico-chemical parameters shown in the table3.


pH

 

Figure 1: pH of groundwater in Neemod village of Neemkathana block

Figure 1 shows that the pH of the groundwater of Neemod village found within (BIS IS 10500: 2012) acceptable limit of 6.5 – 8.5 for the assessment year from Jan-2022 to Dec-2022. A minimum of 7.5, and a maximum of 8.0.

Total alkalinity

 

Figure 2: Total alkalinity in groundwater of Neemod village in Neemkathana block

Figure 2 shows that the total alkalinity for the groundwater of Neemod village was found beyond the BIS (IS 10500: 2012) acceptable limit of 200 mg/L, but all the results are within the permissible limit of 600 mg/L, the results of the test indicate that the value is maximum 394 mg/L while minimum345 mg/L.

Total hardness

 

Figure 3: Total hardness of groundwater in Neemod village of Neemkathana block

Figure 3 shows the assessment of parameter total hardness for the assessment period and the results state that this parameter was found more than the BIS standard. the maximum total hardness of 300 mg/L and the minimum total hardness of 315 mg/L.

Chloride

 

Figure 4: Chloride in groundwater of Neemod village in Neemkathana block

Figure 4 shows that the maximum chloride 115 mg/L and the minimum chloride concentration 89 mg/L is observed. The chloride concentration of groundwater in the Neemod village was observed within the BIS (IS 10500: 2012) acceptable limit of 250 mg/L.

Sulphate


Figure 5: Sulphate in water of Neemod village of Neemkathana block

Figure 5 shows that the maximum sulphate 47 mg/L was found in the month of Sept-2022 and the minimum of 35 mg/L sulphate is found in the month of April, and Dec-2022. The sulphate concentration in groundwater of Neemod village is observed higher than the BIS (IS 10500: 2012) acceptable limit of 200 mg/L. 

Nitrate

 

Figure 6: Nitrate in groundwater of Neemod village in Neemkathana block

Figure 6 shows that maximum nitrate 73 mg/ and the minimum 47 mg/L. Test result reveals that the nitrate concentration of groundwater in the Neemod village observed are within the BIS (IS 10500: 2012) acceptable limit of 47 mg/L.                                               

Fluoride

 

Figure 7: Fluoride in groundwater of Neemod village of Neemkathana block

Figure 7 shows that the maximum fluoride 0.98 mg/L found in the month of Dec-2022 and the minimum fluoride 0.7/mg/L.

Total Dissolved Solids

 

Figure 8: TDS in groundwater of Neemod village of Neemkathana block

Figure 8 shows that the Total Dissolved Solids (TDS) variation for the assessment period Jan 2022 to Dec-2022 is 901 mg/L-992 mg/L. Test result reveals that the total dissolved solid (TDS) in the groundwater of the Neemod village observed higher than the BIS (IS 10500: 2012) acceptable limit of 500 mg/L.

Conclusion Some areas of the Neemkathana block is rich of minerals, and large area covers open cast mining Anthropogenic, and geogenic are both factors deteriorating the quality of groundwater. The total alkalinity, total hardness, nitrate, fluoride, and TDS for the groundwater of Neemod village were found beyond the BIS (IS 10500: 2012) acceptable limit. The present study for the groundwater parameters will be helpful for the villagers to monitor the quality of the selected source for drinking water.
References
1. Amante, C. & B. W. Eakins,B.W. (2009, March). ETOPO1 1 Arc-Minute Global Relief Model: Procedures, Data Sources and Analysis. NOAA Technical Memorandum NESDIS NGDC-24, p,19. 2. BIS. (1991). Indian standard drinking water- specification (First Revision). Bureau of Indian Standards. New Delhi 110002.BIS. (2012). Indian Standard drinking water specifications IS 10500: 2012second revision. Bureau of Indian Standards. New Delhi 110002. 3. Census 2011. (2022). Rajasthan Population 2011 – 2022. Retrieved from https://www. census2011.co.in/census/state/rajasthan.html. 4. Frencken, J.E. (1992). Endemic Fluorosis in developing countries, causes, effects and possible solutions. Publication number 91.082, NIPG-TNO, Leiden, The Netherlands, 5. Johns, W. D., & Huang, W. H. (1967). Distribution of chlorine in terrestrial rocks. Geochimica et Cosmochimica Acta, 31,(1), 35-49. doi.org/10.1016/0016-7037(67)90096-8 6. Machchhar,K,C., S. K. Verma,S.K., K. Tanwar, K., Singh,S., Kakodia, A.K., ( 2020). Physio-Chemiaclanalysis of ground water of village Amar Singh Ka Gada of Ghatol Block, Banswara (Rajasthan). International Journal of Engineering Research, Volume 9 (special issue 2), pp. 12-14, ISSN: 2319-6890 (O), 2347-5013 (P). 7. Matthess, G. (1982) The Properties of Groundwater. Department of Environmental Science, John Wiley and Sons Inc., New York, 406 p. 8. Zumdahl, S. S. (2021, February 2). Water. Encyclopedia Britannica. https://www.britannica.com/science/water